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JOURNAL OF THE CHILEAN CHEMICAL SOCIETY

Publisher:
—
ISSN:
0717-9707
Category:
CHEMISTRY, MULTIDISCIPLINARY
Impact factor:
1.6

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2 parsed articles

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Latest articles

DESIGN AND CHARACTERIZATION OF A BILAYER SODIUM ALGINATE/CARBOXYMETHYL CELLULOSE PATCH ENRICHED WITH CANNABIDIOL AND ACTIVATED CARBON FOR POTENTIAL USE IN ACNE TREATMENT

2025-11-10

Maria Angelica Velandia Paris, Emerson Eliecer León Ávila, Hector David Garzón

This research explores the use of natural polymers as a sustainable alternative to synthetic polymers for developing patches with diverse applications. We created a bilayer patch utilizing sodium alginate (SA) and carboxymethylcellulose (CMC) as natural polymers. Each layer contained an active ingredient: cannabidiol (CBD) in the SA layer and activated carbon (AC) in the CMC layer. CBD and AC were chosen due to their potential as natural treatments for skin conditions like acne. The SA layer was formed using ionic gelation, while the CMC layer was created through compression, both considered eco-friendly methods. The mechanical properties of the patch were evaluated, showing the SA layer had a breaking strength of 11.617 N ± 0.2839, and the CMC layer had a strength of 12.36 N ± 0.1300. Both layers exhibited effective swelling capacity for exudate containment, with swelling percentages of 75.78% ± 1.120 for SA and 76.84% ± 1.171 for CMC. The morphology of the layers met expectations. To quantify the amount of CBD in the patch, high-performance liquid chromatography was employed, optimizing separation conditions based on the column used. The analysis revealed that the SA layer contained 2.08 mg of CBD. The analytical method proved accurate for quantifying CBD in various patch samples. In summary, the developed bilayer patch, using natural materials and sustainable techniques, presents a viable alternative to conventional acne treatments. It demonstrates suitable mechanical properties and effective CBD release, aligning with greener and more sustainable practices.  

A RAPID AND GREEN FLOW INJECTION METHOD FOR THE SPECTROPHOTOMETRIC DETERMINATION OF AL IN AQUEOUS MATRICES

2025-11-10

Cesar Soto, Renato Saavedra, Cristian Fuentes, Catalina Morales

A novel spectrophotometric method for the determination of aluminum (III) in aqueous samples was developed, validated, and optimized, based on the complex formation, between the analyte and Chromo azurol S using flow injection (FI) system. A five factor central composite design (CCD) using the response surface methodology (RSM) was employed to optimize the experimental reaction variables. The resulting second order polynomial model was found to be highly statistically significant, cofirming its excellent fit to the experimental data. Under the optimized conditions, the method demostrated satisfactory accuracy and precisión. The method s robustness was confirmed using a Youden-Steiner test, and was successful applicated and validated to tap wáter samples. The FI method shows advantages over the batch conventional operation, such as high sensitivity, low volume simple consumption, and high sample throughput (40 samples hr -1 ). Also achieved a high analytical GREEnness metric (AGREE) and blue applicability grade index (BAGI), which confirms its ecological quality and practicality. This work provides a rapid, cost-effective, and reliable analytical tool for the determination of aluminium in aqueous matrices.