2026-03-16
N.B. Bakhtybayev, K.T. Atageldiyev, O.A. Abil, A.S. Bakhtybayeva, S.Ye. Suiintayeva
The study presents an investigation of the consequences of explosive impacts during blasting operations at the Zhairem deposit using numerical modeling in the Ansys LS-DYNA software package. Based on literature data and the physico-mechanical properties of rock materials, two modeling scenarios were implemented: the explosion of a single blast hole and a group of blast holes. Dependencies of internal and kinetic energies, displacements, velocities, and accelerations of the rock mass, as well as the distribution of stresses and pressures within the rock, were obtained. It was shown that the maximum equivalent stress during the explosion of a single hole reaches 923.73 MPa, corresponding to the zone of intensive rock mass destruction. For a group of blast holes, energy release increases by several orders of magnitude, reaching 1.2×10⁹ J. Characteristic phases of energy transformation and blast wave dynamics were identified, allowing the assessment of hazardous zones and potential consequences of unauthorized explosions. The results of the study can be used to improve the safety of blasting operations and to predict the impact of air-blast overpressure on buildings and structures.
2026-03-11
О.А. Miryuk
The article presents the results of geopolymer technology development and a study of the performance of lightweight concrete based on a porous aggregate. The purpose of the study is to identify the transformations in composition and structure during the formation and operational testing of porous geopolymer concrete. The porous aggregate and binder are synthesized from molding mixtures of related composition containing sodium liquid glass and finely dispersed from thermal power plants' waste (fly ash and aluminosilicate microsphere). A thermal curing mode for concrete is proposed to ensure the formation of a porous structure with satisfactory resistance to mechanical stress and water. Phase transformations are studied during thermal synthesis of geopolymer material, with prolonged exposure of concrete to water and solutions of magnesium sulfate and sodium. Preliminary economic calculations are performed, indicating the advantages of porous geopolymer concrete compared to cement concrete based on expanded clay. The porous concrete based on geopolymer binder is intended for the production of energy-efficient wall products.
2026-03-10
A. Orakbayev, O. Jumaewa, N. Usanbayev, H. Ataew, Sh. Namazov, U. Alimov, M. Rejepowa, S. Shamuratov
Humus-containing organic and organo-mineral fertilizers play a key role in increasing soil fertility due to their high water-holding capacity, improved water permeability, and ability to reduce phosphorus fixation by calcium and magnesium ions in calcareous soils and by sesquioxides in acidic soils. Organic matter from livestock waste, peat, and brown coal can enrich fertilizers with humus. However, plant residues such as aspen bark, agricultural husks, and licorice root meal are among the most effective additives to produce organic fertilizers. The present study evaluates the synthesis of phosphorus-humus fertilizers in grain form using indicator phosphate rocks discovered in the Kyzylkum deposit, Turkmenistan, and oxidized licorice paste, treated with hydrogen peroxide and acetic acid. The methodology lab experiment consisted of three steps. In the first step, the oxidation behavior of finely ground licorice meal (particle size < 0.1 mm) was investigated using an aqueous hydrogen peroxide solution and acetic acid at mass ratios relative to the organic fraction of the licorice meal in the range of H 2 O 2 : CH 3 COOH = 100 : (10–20) : (0.1–1). In the second step, the phosphate rock was decomposed by 92% sulfuric acid, requiring 30-80% equivalent amounts for monocalcium phosphate. In the third step, the resulting products were mixed with the oxidized licorice paste at a ratio of 100:10:1. This paper evaluates the optimal conditions for processing the phosphorus-humus fertilizer, also producing flowcharts for processing, such as phosphate, provided by each resource. The efficiency of this new technology is presented. The results suggest that low rock phosphate and waste licorice root are environmentally friendly and can be recommended as an alternate tool to reduce the use of high-consumption chemical fertilizers or time consuming conventional composting process.
2026-03-03
Z. Kurayazov, A. Ollaberganova, M. Jabbarov, U. Matnazarov, R. Babajanova
Below is a scientific article explaining the results of a comprehensive study on the desorption of fluoride from mineralized waste (MM) of the Central Kyzylkum phosphate deposits in an acidic environment, studied by experiments and mathematical modeling. The interaction between fluorapatite present in MM and acidic wastewater (AWW) was studied in detail. Acidic components in AWW, mainly free fatty acids, promote the decomposition of fluoride in MM through ion exchange mechanisms. Experiments were performed at 333 K with 30 minutes of mixing for different AWW: MM mass ratios from 100:10 to 100:40. The initial pH of the MM samples was close to neutral, while the pH of the AWW was 2.2; therefore, the pH in the mixtures was acidic. Values of qₑ (fluoride adsorbed per unit mass) and Cₑ (equilibrium fluoride concentration) were calculated for each mixture. Using these data, a regression graph was plotted according to the Langmuir adsorption model. A linear equation obtained from the graph gave q max = 7.48 mg/g and K L = 0.027 L/mg. An R² value of 0.93484 obtained from the Langmuir equation showed that the model and experimental results are in good correlation. Fluoride ions in AWW can be converted into HF gas by strong acids and released into the atmosphere. The identification of reaction products allowed them to propose a mechanism of decomposition. Two different streams of industrial wastes, MM and AWW, were combined in the current work, and this combination allowed the development of new technological solutions.
2026-02-23
D.R. Shaidalina, B.A. Baitimbetova, K.S. Astemessova, G.K. Turlybekova, B.G. Topanov, D.V. Bukhvalov, N.A. Chuchvaga, К.А. Mit’, А.S. Serikkanov
This work presents the synthesis of carbon nanofilaments obtained through the decomposition of graphite in methane plasma with argon admixture. The resulting nanostructures exhibit an amorphous configuration and remain transparent across the visible spectrum, making them attractive candidates for optical and optoelectronic applications. Atomic force microscopy revealed that the filaments form a compact, vertically oriented network on the substrate surface, while Raman spectroscopy provided information on their local bonding environment. Morphologically, the carbon filaments display flattened, ribbon-like forms, and their densely packed columnar structures reach an average length of ~36 nm. The optical transmission spectrum showed transmittance of ~65% near 400 nm, ~75% within the visible region, and nearly 80% in the near-infrared range, gradually increasing toward longer wavelengths. This degree of transparency in the visible spectrum is sufficient for practical device applications. When the incident light wavelength is comparable to or smaller than the inter-filament spacing (100–500 nm), light propagation occurs through reflections from the filament walls. The optical band gap of the structures was determined to be ~2.85 eV. Overall, the analysis of structural and optical properties confirms the successful fabrication of amorphous carbon nanofilaments, highlighting their strong potential for integration into advanced optoelectronic systems.
2026-01-28
V.N. Volodin, S.A. Trebukhov, A.O. Mukangaliyeva, X.A. Linnik, A.V. Nitsenko, N.M. Burabayeva
Based on the values of the partial pressures of magnesium above dimagnesium stannide and melts with tin, determined by the boiling point method (isobaric and isothermal variants, respectively) and tin, calculated by numerical integration of the Gibbs - Duhem equation in accordance with known expressions, the thermodynamic functions were determined: changes in entropy, enthalpy, and free energy of evaporation. Methods to determine the vapor pressure of isobaric and isothermal variants of the boiling point method and calculate thermodynamic values are described. The dependences of the values of partial vapor pressure of magnesium and tin were determined, based on which the energy functions were determined. The measurement error was 7.07%. Data on the change in evaporation entropies are presented graphically. An increase in the partial entropies of evaporation of magnesium and tin was noted with a decrease in their content in the alloy (each) to less than 20 at. %. Extremes are noted: a maximum for magnesium and a minimum for tin at a concentration corresponding to the stoichiometric composition of dimagnesium stannide (60 at. % Мg). The latter indicates the presence of a dissociating compound in the liquid phase that affects evaporation. The values of the change in enthalpy and Gibbs free energy of evaporation are tabulated. It was established that the values of partial and integral enthalpies and Gibbs free energy of vaporization monotonically increase from Mg to Sn in accordance with second-degree dependencies on the concentration of components in the alloy and linearly (Gibbs energy) with temperature. The very small change in the integral value of the free energy of evaporation of magnesium (0.03 ± 0.002 kJ/mol) at 1373 K (1100 °C) indicates a practical coincidence with the boiling point of magnesium. The energy functions of evaporation of magnesium-tin melts will supplement the thermodynamic database and can be used for thermal engineering calculations in the design of distillation processes and apparatus.