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Jordan Journal of Chemistry

Publisher:
—
ISSN:
1814-9111
Category:
CHEMISTRY, MULTIDISCIPLINARY
Impact factor:
0.4

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2 parsed articles

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Latest articles

Computational Evaluation of Phytochemicals from Oxalis corniculata and Oxalis latifolia as Potential Modulators of the Human Pregnane X Receptor

2025-12-30

Ram Lal (Swagat) Shrestha, Shiva M.C., Ashika Tamang, Manila Poudel, Sujan Dhital, Nirmal Parajuli, Safal Adhikari, Aakar Shrestha, Timila Shrestha, Samjhana Bharati, Binita Maharjan, Bishnu Prasad Marasini, Jhashanath Adhikari Subin

The genus Oxalis is known for its diverse medicinal properties, offering phytochemicals with therapeutic applications. This study investigates the potential of these compounds as modulators of human pregnane X receptor (hPXR), a key regulator of genes involved in drug metabolism and detoxification. Its activation affects the body’s response to foreign chemicals (xenobiotics), including drugs, influencing drug-drug interactions, pharmacokinetics, and toxicity. Using molecular docking techniques, 36 compounds selected from Oxalis corniculata and Oxalis latifolia were evaluated for their interaction with hPXR. The phytocomponents, squalene, diosmetin-7-O-beta-D-glucopyranoside, apigenin-7-O-glucoside, rhapontin, and luteolin-7-O-glucoside exhibited stronger binding affinities compared to the receptor's native ligand, suggesting a better role in modulating hPXR activity. Protein-ligand interaction analysis of five ligands revealed hydrophobic, hydrogen bonds, and salt bridges, with key residues, TRP299, HIS407, LEU209, LEU411 and PHE288, stabilizing ligand binding. ADMET analysis predicted favorable drug-like properties for these compounds, supporting their further development. Squalene, diosmetin-7-O-beta-D-glucopyranoside, and apigenin-7-O-glucoside were identified as promising candidates due to their strong binding and acceptable pharmacokinetic profiles. This computational evaluation provides insights into Oxalis phytochemicals as potential natural modulators of hPXR, with implications for therapeutic interventions and future experimental studies.

Thermodynamic Calculations of a Binary System based on Ammonium Sulfamate and Urea Derivatives

2025-12-30

Alexander Kazachenko, Yaroslava Berezhnaya

Deep eutectic solvents are widely used in various science related fields including organic chemistry, electrochemistry and etc. In this work, we present results regarding preparation of new deep eutectic solvents - a mixture of ammonium sulfamate (ASA) with urea (U) and its derivatives (methyl urea (MetU), ethyl urea (EtU), hydroxyethyl urea (HEtU). Melting points of various components eutectic mixtures are determined and phase diagrams are presented. It is shown that the eutectic point temperature of the ammonium sulfamate with urea (urea mole fraction 0.3) mixture is 361°K, with methyl urea mixture is 358°K (mole fraction 0.7), with ethyl urea mixture - 362°K (mole fraction 0.6), with the hydroxyethyl urea - 354°K (mole fraction 0.6). Based on obtained experimental data a complex calculation of the thermodynamic characteristics of the system (enthalpy, entropy, chemical potential, effective interaction parameter) was carried out. The chemical potentials of a deep eutectic solvent were calculated using ideal and real solution models.