2026-03-31
Harrison J Barnett, Anthony Hill
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00300A, Communication Harrison J Barnett, Anthony Hill The carbido complex [Rh 2 (μ-C)Cl 2 (μ-dppm) 2 ] reacts with triphenyl cyclopropenium hexafluorophosphate to afford the exo-metallated metallacyclopentadiene salt [Rh 2 (μ-C 4 Ph 3 )Cl 2 (μ-dppm) 2 ]PF 6 . via formal insertion of a metal-carbon multiple bond into the cyclopropenium ring. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-30
Yun Cao, Mengting Zhao, Yuxuan Zhang, Chunyin Ye, Junuo Zhang, Yan Wang
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00554C, Paper Yun Cao, Mengting Zhao, Yuxuan Zhang, Chunyin Ye, Junuo Zhang, Yan Wang A three-dimensional MOF, {[Cd(bpdc)(L1)]·5H2O}n (1) (H2bpdc = biphenyl-4,4’-dicarboxylic acid; L1 = 1,1’-((2,4,6−trimethyl-1,3-phenylene)bis(methylene))bis(2-methyl-1H-imidazole)), was synthesized under hydrothermal conditions and comprehensively characterized. Luminescence studies reveal that complex 1 exhibits a distinct fluorescence... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-30
Hui Ni, Zhen Ma, Jianyi Qin, Xin Zhang, Jing Zhang, Bin Zhao
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00533K, Paper Hui Ni, Zhen Ma, Jianyi Qin, Xin Zhang, Jing Zhang, Bin Zhao The development of highly efficient and cost-effective non-precious metal electrocatalysts for the hydrogen evolution reaction (HER) in alkaline solutions remains a significant challenge in green hydrogen production through water electrolysis.... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-29
Tomohiro Okita, Ryoma Uchida, Atsushi Shimojima, Takamichi Matsuno
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D5DT03043A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Tomohiro Okita, Ryoma Uchida, Atsushi Shimojima, Takamichi Matsuno The properties of nanoporous metal oxides depend on their pore structure and the internal structure of the pore walls, and precise control of such factors is crucial. In particular, single-crystalline... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-29
Guan-Ruei Chen, Wan-Zhen Xiaoa, Yen-Han Huang, Chia-Wei Yang, Chi-Shen Lee
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D5DT02970H, Paper Guan-Ruei Chen, Wan-Zhen Xiaoa, Yen-Han Huang, Chia-Wei Yang, Chi-Shen Lee New multinary selenides A3B14Se24 (A = Sn/Pb; B = In/Sb/Bi) were discovered by exploratory synthesis in the (Sn/Pb)–In–(Sb/Bi)–Se systems. Single-crystal X-ray diffraction established this structure type for Pb3In5Sb9Se24, Pb3In6Sb8Se24, Sn3In5Sb9Se24,... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-27
Jonas Riedmaier, Caecilia Maichle-Moessmer, Reiner Anwander
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00453A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jonas Riedmaier, Caecilia Maichle-Moessmer, Reiner Anwander Cerous triazolates and tetrazolates were synthesised utilising Ce[N(SiMe3)2]3 as precursor. The transaminiation with HtzMe,Me (tzMe,Me = 3,5-dimethyl-1,2,4-triazolyl), HtrzBz (trzBz = 1,2,3-benzotriazolyl) and HtetPh (tetPh = 5-phenyltetrazolyl) gave insoluble, white solids... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-27
Liyuan Sang, Qianru Ye, Yu Shi, Heng Liu, Bing Wang, Wenxin Lin, Quan Hu
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00195E, Paper Liyuan Sang, Qianru Ye, Yu Shi, Heng Liu, Bing Wang, Wenxin Lin, Quan Hu A multimodal tumor therapeutic system, termed Mn&DOX@Ce-BDA, was successfully constructed by incorporating manganese ions (Mn 2+ ) and chemotherapeutic agent doxorubicin (DOX) into a cerium-based metal–organic framework (Ce-BDA). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-26
Kris Mark Altus, Samantha Kathleen Furfari, Joe Goodall, Matthew Robert Gyton, Jack Heaton, Chloe Johnson, Alasdair I. McKay, Mads Sondrup Møller, Sebastian D Pike, Andrew S Weller
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00444J, Tutorial Review Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Kris Mark Altus, Samantha Kathleen Furfari, Joe Goodall, Matthew Robert Gyton, Jack Heaton, Chloe Johnson, Alasdair I. McKay, Mads Sondrup Møller, Sebastian D Pike, Andrew S Weller In crystallo solid/gas solid-state molecular organometallic (SMOM) chemistry offers unique opportunities in organometallic synthesis and catalysis. The methodology provides routes to synthesise complexes that are challenging to isolate and characterise... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-25
Eleonora Botter, Valentina Lauteri, Alessandro Rubbi, Laura Orian, Matteo Forner, Valentina Gandin, Nicola Demitri, Vincenzo Canzonieri, Flavio Rizzolio, Enrico Cavarzerani, Fabiano Visentin, Thomas Scattolin
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00680A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Eleonora Botter, Valentina Lauteri, Alessandro Rubbi, Laura Orian, Matteo Forner, Valentina Gandin, Nicola Demitri, Vincenzo Canzonieri, Flavio Rizzolio, Enrico Cavarzerani, Fabiano Visentin, Thomas Scattolin The development of effective and selective metal-based chemotherapeutics remains a central challenge in ovarian cancer treatment, particularly in addressing resistance to platinum agents. Herein, we report the design, synthesis, and... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-25
Dongting Wang, Shan Ding, Su'e Chen, Dongyu Shan, Chunjie Jiang, Xinning Zhang
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00129G, Paper Dongting Wang, Shan Ding, Su'e Chen, Dongyu Shan, Chunjie Jiang, Xinning Zhang Ethanol sensing with enhanced humidity tolerance was achieved using octahedral nanostructures of pure SnO 2 , Sb-doped SnO 2 , and Pt-loaded Sb-SnO 2 synthesized via a solvothermal method. All... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-24
Wei Chen, Wanli Tian, Kai Tao
Dalton Trans. , 2026, Accepted Manuscript DOI : 10.1039/D6DT00463F, Paper Wei Chen, Wanli Tian, Kai Tao Transition metal phosphides (TMPs) have emerged as highly active bifunctional electrocatalysts, owing to their excellent conductivity and tunable electronic structure. However, a major bottleneck for TMP‑based catalysts is their limited... The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-23
Xin Su, Chen Lin, Mengxin Liu, Xinan Shi, Daocheng Pan
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00288A, Paper Xin Su, Chen Lin, Mengxin Liu, Xinan Shi, Daocheng Pan QLED based on 10% F-doped SnO2 ETL exhibit a peak external quantum efficiency of 16.55% and a maximum luminance of 129,117 cd m −2 To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-19
Wenjuan Li, Yuanping Li, Yanting Shi, Hui Xu, Linyun Zhu, Xinyu Chen, Xiaopei Li, Jianfeng Yan, Lantao Liu, Yuanming Li
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00371K, Communication Wenjuan Li, Yuanping Li, Yanting Shi, Hui Xu, Linyun Zhu, Xinyu Chen, Xiaopei Li, Jianfeng Yan, Lantao Liu, Yuanming Li This work presents an efficient synthesis of 1,3- and 1,1′-diarylated ferrocenes, coupled with the construction of a strained main-chain ferrocene-based macrocycle. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-18
Xiong-Feng Ma, Zhuang Miao, Xiaodun Deng, Hongping Hou, Wenke Li, Yangyang Liu, Chengyu Xi, Rong Zhang, Zhihuan Zhou, Chaoqian Ai, Hongliang Du
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D5DT01720C, Paper Xiong-Feng Ma, Zhuang Miao, Xiaodun Deng, Hongping Hou, Wenke Li, Yangyang Liu, Chengyu Xi, Rong Zhang, Zhihuan Zhou, Chaoqian Ai, Hongliang Du Synthesis of 2D Co( II ) MOF shows red-light photocatalysis in oxidation reaction. Ultrasonication-derived MOF nanoparticle has enhanced activity via exposed Co( II ) sites, lower charge-transfer resistance, and efficient electron-hole separation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-18
Nan-Nan Huo, De-Ke Zhang, Yu-Zhen Wei, Peng Luo, Si Li
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00475J, Paper Nan-Nan Huo, De-Ke Zhang, Yu-Zhen Wei, Peng Luo, Si Li Novel luminescent bowl-shaped copper cluster synthesized via ligand engineering strategy for fluorescent detection of NO 3 − with a limit of detection of 0.76 µM. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-18
Sarah Kromer, Liam J. Dress, Evgeny O. Danilov, Livia I. Cohen, Adrienne P. Faulkner, Felix N. Castellano
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00411C, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Sarah Kromer, Liam J. Dress, Evgeny O. Danilov, Livia I. Cohen, Adrienne P. Faulkner, Felix N. Castellano Thiol–pyridine and thiol–quinoline bridging ligands reduce the metal-metal separation in Pt( II ) dimers with tridentate cyclometalating ligands. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-18
Jordi R.-Galindo, Jhon Sebastian Oviedo-Ortiz, Antonino Arenaza-Corona, Adrián Ruíz-Martínez, Juan S. Serrano-García, Simón Hernández-Ortega, Marcos Flores-Alamo, T. Keith Hollis, David Morales-Morales
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00442C, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Jordi R.-Galindo, Jhon Sebastian Oviedo-Ortiz, Antonino Arenaza-Corona, Adrián Ruíz-Martínez, Juan S. Serrano-García, Simón Hernández-Ortega, Marcos Flores-Alamo, T. Keith Hollis, David Morales-Morales Base-free metalation of imine-derived POCOP ligands yields Ni( II ) pincer complexes alongside imine- and aldehyde-type addition products, whereas base enables selective formation of the pincer complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-17
Zhuocheng Xue, Shubo Cheng, Huafeng Zhang, Jun Zhu, Zao Yi
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00208K, Paper Zhuocheng Xue, Shubo Cheng, Huafeng Zhang, Jun Zhu, Zao Yi As demonstrated by FDTD simulations, the proposed absorber attains an average absorption rate that exceeds 90% across the 280–3138 nm wavelength range. This absorber also exhibits remarkable performance in the role of a thermal emitter. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-16
Yoseph Kim, Ji Hye Lee, Hyeongkwon Moon, Himchan Mo, Hyonseok Hwang, Junseong Lee, Jun Hui Park, Youngjo Kim, Myung Hwan Park
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00428H, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Yoseph Kim, Ji Hye Lee, Hyeongkwon Moon, Himchan Mo, Hyonseok Hwang, Junseong Lee, Jun Hui Park, Youngjo Kim, Myung Hwan Park Xanthene-anchored open and closed dinuclear indium complexes reveal that controlled chromophore separation enhances radiative decay and suppresses non-radiative relaxation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-16
Mahdieh Maleki, Lilla Nánai, Sergey K. Zharmukhamedov, Robabeh Bagheri, Nader Akbari, Elena V. Zadneprovskaya, Roman A. Voloshin, Klara Hernadi, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00486E, Paper Mahdieh Maleki, Lilla Nánai, Sergey K. Zharmukhamedov, Robabeh Bagheri, Nader Akbari, Elena V. Zadneprovskaya, Roman A. Voloshin, Klara Hernadi, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour An oxygen-evolution reaction electrocatalyst was reported by first growing a vertically aligned carbon nanotube forest, and a NiFeCo (hydr)oxide coating onto the CNT forest. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-13
Nataliya Krutyak, Damian Wlodarczyk, Irina Kudryavtseva, Yaroslav Zhydachevskyy, Diana Vistorskaja, Dmitry Spassky
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D5DT03126E, Paper Nataliya Krutyak, Damian Wlodarczyk, Irina Kudryavtseva, Yaroslav Zhydachevskyy, Diana Vistorskaja, Dmitry Spassky The structure and luminescence properties of novel NASICON-type Na 3.6 Y 1.8− x Sc x (PO 4 ) 3 solid solutions have been studied. The enhanced intensity and thermal stability of exciton emission in these solutions are related to structural disorder. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-12
Anubhab Das, Sayantan Mukhopadhyay, Sagrika Rajput, Sharanappa Nembenna
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00286B, Paper Anubhab Das, Sayantan Mukhopadhyay, Sagrika Rajput, Sharanappa Nembenna Magnesium catalysis: a β-diketiminate magnesium hydride efficiently catalyzes the chemoselective hydroboration of α,β-unsaturated ketones. Stoichiometric experiments and an isolated intermediate elucidate the proposed catalytic cycle. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-06
Wenting Lv, Xuliang Jiang, Guangmei Wei, Ruochen Wei, Fengmin Sun, Ruihua Zhang, Yanlu Guo, Xiaojuan Chai, Weiyong Jiao, Baoliang Lv
Dalton Trans. , 2026, 55 ,5301-5312 DOI : 10.1039/D6DT00240D, Paper Wenting Lv, Xuliang Jiang, Guangmei Wei, Ruochen Wei, Fengmin Sun, Ruihua Zhang, Yanlu Guo, Xiaojuan Chai, Weiyong Jiao, Baoliang Lv SmMnO x coupling effectively enhances the low-temperature NH 3 -SCR activity and SO 2 resistance of Cu-SSZ-13. This improvement is attributed to adsorption–activation synergy, redox synergy, and cooperative defense between the zeolite and oxide. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-06
Lucretia Rotari, Valeria Vergine, Giel Berden, Jos Oomens, Barbara Chiavarino, Davide Corinti, Maria Elisa Crestoni
Dalton Trans. , 2026, 55 ,5290-5300 DOI : 10.1039/D5DT03119B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Lucretia Rotari, Valeria Vergine, Giel Berden, Jos Oomens, Barbara Chiavarino, Davide Corinti, Maria Elisa Crestoni Zn complexes of naringenin and its chalcone were analyzed by ion spectroscopy, showing similar IR spectra coherent with an isomerization equilibrium. Gas-phase activation causes oxidative Zn 0 loss yielding two isomers via a Zn-promoted phenol shift. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-03-06
Jianwu Wen, Fuxiang Chai, Yonghu Bao, Mengxin Tao, Zeming Huang, Xiancui Zhu, Qingbing Yuan, Shaowu Wang
Dalton Trans. , 2026, 55 ,5369-5381 DOI : 10.1039/D6DT00212A, Paper Jianwu Wen, Fuxiang Chai, Yonghu Bao, Mengxin Tao, Zeming Huang, Xiancui Zhu, Qingbing Yuan, Shaowu Wang Homodinuclear rare-earth metal alkyl complexes supported by an indol-2-yl-based pincer ligand exhibit diverse reactivity toward N-/O-containing compounds, resulting in the formation of metal complexes with different functional groups. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-02-27
Wesley W. Kramer, Thomas R. Sheridan, Jorge Pérez-Vázquez, Christophe A. Boivin, Amanda M. Browne, Catherine G. Logan, Brian C. Sanders
Dalton Trans. , 2026, 55 ,5197-5209 DOI : 10.1039/D5DT02433A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wesley W. Kramer, Thomas R. Sheridan, Jorge Pérez-Vázquez, Christophe A. Boivin, Amanda M. Browne, Catherine G. Logan, Brian C. Sanders The presence of pendant cationic functional groups in group 7 fac -tricarbonyl complexes produces unusual axial-halide substitution reactivity. The effects of the metal, axial halide, and solvent on the ligand substitution equilibrium are presented. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-02-27
Simon M. Mittag, Jonas Klopf, Alexander V. Virovets, Eugenia Peresypkina, Hans-Wolfram Lerner, Holger Helten, Matthias Wagner
Dalton Trans. , 2026, Advance Article DOI : 10.1039/D6DT00412A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Simon M. Mittag, Jonas Klopf, Alexander V. Virovets, Eugenia Peresypkina, Hans-Wolfram Lerner, Holger Helten, Matthias Wagner B 2 E 2 -doped PAHs (E = O, NR) were synthesized: Catalyst control (Au( I ) vs. amines) steers the cyclization toward either symmetric B 2 O 2 -binaphthyls or iso -B 2 E 2 -naphthylbenzofulvenes, exhibiting bright blue-green emission. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-01-30
Larissa Chimilouski, Sheetal Ranaut, William Henrique Slominski, Patrícia Salvador Tessaro, Gilson DeFreitas-Silva, Edmar Martendal, Cláudio N. Verani, Shivnath Mazumder, Fernando Roberto Xavier
Dalton Trans. , 2026, 55 ,5117-5129 DOI : 10.1039/D5DT02798E, Paper Larissa Chimilouski, Sheetal Ranaut, William Henrique Slominski, Patrícia Salvador Tessaro, Gilson DeFreitas-Silva, Edmar Martendal, Cláudio N. Verani, Shivnath Mazumder, Fernando Roberto Xavier The catalytic oxidation of benzyl alcohols was optimized based on multivariate analysis, and advanced DFT calculations support distinct mechanistic pathways for each metalloporphyrin. The content of this RSS Feed (c) The Royal Society of Chemistry
2026-01-07
Anthony J. Campanella, Amanda Gin, Siyoung Sung, Cassidy E. Jackson, Roxanna Martinez, Ökten Üngör, Srikanth Dasari, Andrew Ozarowski, Indrani Bhowmick, Joseph M. Zadrozny
Dalton Trans. , 2026, 55 ,5139-5150 DOI : 10.1039/D5DT02920A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Anthony J. Campanella, Amanda Gin, Siyoung Sung, Cassidy E. Jackson, Roxanna Martinez, Ökten Üngör, Srikanth Dasari, Andrew Ozarowski, Indrani Bhowmick, Joseph M. Zadrozny A series of Mn( II ) complexes are found to exhibit strong temperature-dependent EPR spectra that eclipse the temperature sensitivity of the nitrogen vacancy qubit in a diamond lattice. The content of this RSS Feed (c) The Royal Society of Chemistry