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Nature Chemistry

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8 parsed articles

Last update: 2026-09-21

Latest articles

Weaving two-dimensional peptide crystals

2026-09-18

Bidyut K. Kundu, Andy I. Nguyen

Peptides can assemble into two-dimensional ultrathin materials with programmable structures and functions, but maintaining crystallinity and stability is challenging. Now, a metal-directed assembly strategy enables mechanical weaving of peptides to provide highly durable and modular two-dimensional peptide crystals with molecular-level precision.

DOI: 10.1038/s41557-026-02252-0

Autonomous migration of a phosphate group along glycerol and inositol scaffolds driven by a phosphodiester reaction cycle

2026-09-18

Patrick Alexander Hoffmann, Suchismita Saha, Steffen Volk, Jing Sun, Andreas Englert, Max von Delius

Small-molecule walkers that combine autonomy with kinetic asymmetry have remained elusive. Now, simple phosphoric acid esters are shown to drive a non-enzymatic reaction cycle that autonomously migrates a phosphate group along five hydroxy footholds, expanding the scope of synthetic molecular machinery.

DOI: 10.1038/s41557-026-02240-4

F - centre charge state and dynamism govern oxide electrocatalytic selectivity

2026-09-17

Xiaoyuan Zhang, Danil Bukhvalov, Tiannan Su, Chenchen Fang, Liming Dai, Shuo San, Huiru Duan, Yaya Wang, Kai Liu, Junjie Cui, Yuxiang Hua, Liang Xue, Zhen Hou, Wenyao Zhang, Pan Xiong, Yongsheng Fu, Jingwen Sun, Junwu Zhu

The charge state of oxygen vacancies, manifested as distinct F centres, remains an underexplored descriptor for electrocatalytic pathway modulation. Now it has been shown that different F centres in ZrO2 regulate oxygen reduction via unique electronic behaviours, establishing F-centre identity as a key indicator for electrocatalytic selectivity.

DOI: 10.1038/s41557-026-02256-w

Nanoscale visualization of plasmon-enhanced hydrogen activation on a Pt(111) surface

2026-09-10

Zhen-Feng Cai, Meghna A. Manae, Zi-Xi Tang, Jun-Xian Zhang, Yao Zhang, Jeremy O. Richardson, Naresh Kumar

Visualizing plasmon-enhanced H2 activation and propagation on catalytic surfaces remains challenging because conventional spectroscopies lack nanoscale resolution. Now it has been shown that tip-enhanced Raman spectroscopy maps H2 activation within an Ag tip–Pt(111) nanocavity and reveals H atoms propagating hundreds of nanometres across Pt(111) through a collective crowd effect.

DOI: 10.1038/s41557-026-02245-z

Ionic clusters as high-connectivity secondary building units for crystalline porous organic salts

2026-09-08

Yu-Lin Lu, Yishuo Chen, Hang Qu, Laiyu Zhang, Megan O’Shaughnessy, Thomas Fellowes, Andrew I. Cooper

Rigid coordination bonds readily generate highly connected secondary building units in metal–organic frameworks, but weaker and less directional interactions have rarely afforded comparable architectures in molecular crystals. Now ammonium halide ion pairs are shown to aggregate into discrete clusters that function as soft secondary building units, opening a route to non-metallic organic frameworks with diverse topologies.

DOI: 10.1038/s41557-026-02248-w

Directed heterogeneous hydride transfer enables selective CO 2 reduction using a Janus palladium membrane electrode

2026-09-07

Xiaosong Hu, William Boyd, Feihu Wang, Aaron Diefendorf, Owen Cowling, Yujie Sun

Electrochemical CO2 reduction is typically constrained by proton-coupled electron transfer, which couples CO2 conversion with competing H2 evolution. Now it has been shown that a Janus palladium membrane electrode enables selective formate production through heterogeneous hydride transfer, providing access to electrochemical hydride-based reactivity beyond proton-mediated electrocatalysis.

DOI: 10.1038/s41557-026-02243-1

Lower-temperature bulk depolymerization of commercial polymethacrylates

2026-09-02

Richard Whitfield, Victoria Lohmann, Mikhail Agrachev, Hongsik Kim, Hyun Suk Wang, Nethmi De Alwis Watuthanthrige, Nghia P. Truong, Tae-Lim Choi, Gunnar Jeschke, Athina Anastasaki

Chemical recycling of polymers has largely relied on thermally unstable tailor-made materials or highly diluted depolymerization conditions. Now, a bulk main-chain scission pathway enables the rapid, low-temperature depolymerization of polymethacrylates. This methodology can be applied to commercial polymers without the need for preinstalled end-groups or sacrificial co-monomers, allowing high-yield recovery of monomers.

DOI: 10.1038/s41557-026-02232-4